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Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: >2sub>WO<sub>6sub> composite.>2sub>WO<sub>6sub>.The reduced work function improved the transfer and separation of charge carriers, which mainly caused>2sub>WO<sub>6sub>, respectively.>2sub>-to-NH<sub>3sub> conversion.

Keywords: Bi<sub>2sub>WO<sub>6sub>     Cu doping     work function     photocatalytic N<sub>2sub> fixation     chargeseparation    

Reduction potential of the energy penalty for CO capture in CCS

Frontiers in Energy 2023, Volume 17, Issue 3,   Pages 390-399 doi: 10.1007/s11708-023-0864-x

Abstract: CO<sub>2sub> capture and storage (CCS) has been acknowledged as an essential part of a portfolio oftechnologies that are required to achieve cost-effective long-term CO<sub>2sub> mitigation.One of the crucial reasons for this delay lies in the unaffordable penalty caused by CO<sub>2sub> captureFrom the aspects of separation and capture technology innovation, the potential and promising direction

Keywords: CO<sub>2sub> capture and storage (CCS)     CO<sub>2sub> separation     energy penalty    

Nickel(II) ion-intercalated MXene membranes for enhanced H<sub>2sub>/CO<sub>2sub> separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 4,   Pages 882-891 doi: 10.1007/s11705-020-1990-1

Abstract: A membrane-assisted separation is promising in producing high-purity H .The prepared membranes showed excellent H /CO mixture separation performance at room temperature.Separation factor reached 615 with a hydrogen permeance of 8.35 × 10 mol·m ·s ·Pa .During 200-hour testing, the resultant membrane maintained an excellent gas separation without any substantial

Keywords: MXene     H<sub>2sub>/CO<sub>2sub> separation     nickel ions     hollow fiber    

One-Step Synthesis of Structurally Stable CO<sub>2sub>-Philic Membranes with Ultra-High PEO Loading Article

Bin Zhu, Shanshan He, Yadong Wu, Songwei Li, Lu Shao

Engineering 2023, Volume 26, Issue 7,   Pages 220-228 doi: 10.1016/j.eng.2022.03.016

Abstract: >2sub> levels because CO<sub>2sub>-philic membranes have demonstrated significant application potential, especially, for CO<sub>2sub>/light gas separation.In this regard, poly(ethylene oxide) (PEO), which is a representative CO<sub>2sub>-philic material,>2sub>.and CO<sub>2sub>/light gas selectivity at high feed pressure (up to 20 bar).

Keywords: Membrane separation     Gas separation     CO<sub>2sub> capture     CO<sub>2sub>-philic membrane     Poly(ethylene    

growth of a-few-layered MoS on CdS nanorod for high efficient photocatalytic H production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 752-759 doi: 10.1007/s11708-021-0779-3

Abstract: An ultrathin MoS<sub>2sub> was grown on CdS nanorod by a solid state method using sulfur powder assulfur source for photocatalytic H<sub>2sub> production.The characterization result reveals that the ultrathin MoS<sub>2sub> nanosheets loaded on CdS has aThe photoelectrochemical result shows that MoS<sub>2sub> not only are beneficial for charge separation>2sub> on enhancing photocatalytic activity.

Keywords: photocatalytic H<sub>2sub> production     CdS     MoS<sub>2sub> cocatalyst     charge separation    

Effect of TiO

Navid Azizi, Mojgan Isanejad, Toraj Mohammadi, Reza M. Behbahani

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 3,   Pages 517-530 doi: 10.1007/s11705-018-1781-0

Abstract: The effects of the titanium dioxide nanoparticle load on the morphology and CO /CH separation performanceThe incorporation of TiO nanoparticles into the polymeric MMMs improved the CO /CH gas separation performance

Keywords: mixed matrix membrane     TiO<sub>2sub> nanoparticles     PEBAX-1657     CO<sub>2sub>/CH<sub>4sub> separation    

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords: Rh<sub>2sub>O<sub>3sub>     CePO<sub>4sub>     N<sub>2sub>O decomposition    

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords: Mn promotion     nickel catalysts     CO<sub>2sub> methanation     co-methanation of CO and CO<sub>2sub>    

Covering α-Fe

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 6, doi: 10.1007/s11783-017-0957-z

Abstract: Compared with SiMP, its optical absorption and photocurrent density improved 2 times and 4 times, respectivelyThese improved performances could be ascribed to the enhanced photogenerated-charge-separation efficiency

Keywords: Si     α-Fe<sub>2sub>O<sub>3sub>     Photoelectrochemistry     Photogenerated charge separation    

A Storage-Driven CO<sub>2sub> EOR for a Net-Zero Emission Target Article

Yueliang Liu, Zhenhua Rui

Engineering 2022, Volume 18, Issue 11,   Pages 79-87 doi: 10.1016/j.eng.2022.02.010

Abstract: >2sub>) emissions.>2sub> emissions by storing CO<sub>2sub> in oil reservoirs.CO<sub>2sub> EOR—whose main target is to realize net-zero or even negative CO<sub>2sub> emissionsStorage-driven CO<sub>2sub> EOR is superior to conventional CO<sub>2sub> EOR in improving sweepingthan conventional CO<sub>2sub> EOR.

Keywords: CO<sub>2sub>     EOR     Net CO<sub>2sub>     emissions     Dimethyl ether     Storage-driven CO<sub>2sub>     EOR     CO<sub>2sub>     sequestration    

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords: CO<sub>2sub> capture     MgO sorbents     Al<sub>2sub>O<sub>3sub>     CeO<sub>2sub>     flue gas    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

ZnFe<sub>2sub>O<sub>4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO<sub>2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2,   Pages 197-204 doi: 10.1007/s11705-016-1606-y

Abstract: oxygen atoms in the exposed (001) facets, which creates more oxygen vacancies, and thereby improves the separation

Keywords: reduction of CO<sub>2sub>     cyclohexanol     ZnFe<sub>2sub>O<sub>4sub> deposited BiOCl     facet     composite    

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Strategic Study of CAE 2013, Volume 15, Issue 2,   Pages 107-112

Abstract: The structure of SOEC, the recent development of high temperature steam/CO2 co-electrolysis from

Keywords: SOEC     H<sub>2sub>O/CO<sub>2sub> co-electrolysis     syngas     electrolysis efficiency     water electrolysis    

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Strategic Study of CAE 2004, Volume 6, Issue 6,   Pages 63-67

Abstract:

The thermodynamic calculation and analysis of combustion synthesis reaction of Al - Cr<sub>2</sub>O<sub>3</sub> system with AI<sub>2</sub>O<sub>3</sub>and Cr<sub>2</sub>O<sub>3</sub> diluents were conducted, and the effects of reactionstarting temperature T<sub>O</sub>, diluents AI<sub>2</sub>O<sub>3</sub> and Cr<sub>2</sub>O<sub>3</sub> on the adiabatic combustion temperature

Keywords: cermet     combustion synthesis     Al - Cr<sub>2sub>O<sub>3sub> system     thermodynamics     reaction model    

Title Author Date Type Operation

Cu-doped Bi/Bi<sub>2sub>WO<sub>6sub> catalysts for efficient N<sub>2sub> fixation by photocatalysis

Journal Article

Reduction potential of the energy penalty for CO capture in CCS

Journal Article

Nickel(II) ion-intercalated MXene membranes for enhanced H<sub>2sub>/CO<sub>2sub> separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

Journal Article

One-Step Synthesis of Structurally Stable CO<sub>2sub>-Philic Membranes with Ultra-High PEO Loading

Bin Zhu, Shanshan He, Yadong Wu, Songwei Li, Lu Shao

Journal Article

growth of a-few-layered MoS on CdS nanorod for high efficient photocatalytic H production

Journal Article

Effect of TiO

Navid Azizi, Mojgan Isanejad, Toraj Mohammadi, Reza M. Behbahani

Journal Article

Rh<sub>2sub>O<sub>3sub>/hexagonal CePO<sub>4sub> nanocatalysts for N<sub>2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

CO<sub>2sub> methanation and co-methanation of CO and CO<sub>2sub> over Mn-promoted Ni/Al<sub>2sub>O<sub>3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

Covering α-Fe

Jing Gu, Hongtao Yu, Xie Quan, Shuo Chen

Journal Article

A Storage-Driven CO<sub>2sub> EOR for a Net-Zero Emission Target

Yueliang Liu, Zhenhua Rui

Journal Article

Al<sub>2sub>O<sub>3sub> and CeO<sub>2sub>-promoted MgO sorbents for CO<sub>2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article

ZnFe<sub>2sub>O<sub>4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO<sub>2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Journal Article

Development of H<sub>2sub>O/CO<sub>2sub> co-electrolysis in solid oxide electrolysis cell

Fan Hui,Song Shidong,Han Minfang

Journal Article

Thermodynamic Analysis and Reaction Model of Combustion Synthesis in Al-Cr<sub>2sub>O<sub>3sub> Systemwith Al<sub>2sub>O<sub>3sub> and Cr<sub>2sub>O<sub>3sub> Diluents

Zhang Yancheng,Pan Ye,Zhang Chuan

Journal Article